Negative ion production by surface ionization at aluminum-nitride surfaces S. Jans, P. Wurz, R. Schletti, and T. Frohlich In this article, we report on the observation of the formation of negatively charged ions upon reflection from an aluminum-nitride surface. Positive H2 and O2 ions are scattered at small angles of incidence off a single-crystal surface. Charge exchange at the surface yields neutral particles and negative ions in the reflected particle flux. The negative ion fractions are about 15% and 1% for oxygen and hydrogen, respectively. The particle reflection probability is only 2%, which is attributed to the roughness of the surface. _______________ Journal of Applied Physics, 85 (1), 2587-2592, 2000